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where E0' and E0' are the formal potentials of Mn1+/M1 and Mn2+/M2, respectively. 1 2 1 2 The condition in Eq. (5.35) can predict the appropriate potential range for separating the two metal ions. When metal ion Mn+ is deposited by the controlled-current method, the electrode potential during the electrolysis changes in the order 1', 2', 3', 4', 5', 6' in Fig. 5.33 and the next reduction process occurs near the end of the electrolysis. If the solution is acidic and the next reduction process is hydrogen generation, its influence on the metal deposition is not serious. However, if other metal is deposited in the next reduction process, metal M is contaminated with it. In order that two metal ions Mn1+ 1 and Mn2+ can be separated by the controlled-current method, the solution must be 2 acidic and the reduction of hydrogen ion must occur at the potential between the reductions of the two metal ions. An example of such a case is the separation of Cu2+ and Zn2+ in acidic solutions. If two metal ions are reduced more easily than a hydrogen ion (e.g. Ag+ and Cu2+), they cannot be separated by the controlled-current method and the controlled-potential method must be used. free 2d barcode generator for excel Barcode Add -In for Word & Excel Download and Installation
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